Chemistry Professors Receive NSF RUI Awards
July 1, 1998

l to r: Professors Charles Beam, Shannon Martinez, and Kristin Krantzman
The Research in Undergraduate Institutions (RUI) activity is
part of the Foundation's effort to help assure a broad base for
science and engineering research, and thereby enhance the
scientific and technical training of students in undergraduate
institutions. The specific objectives of the RUI program are to:
(1) support high quality research by faculty with active
involvement of undergraduate students, (2) strengthen the research
environment in academic departments that are oriented primarily
toward undergraduate instruction, and (3) promote the integration
of research and education at predominantly undergraduate
institutions.
Through RUI, NSF provides support for research and research
instrumentation for investigators in non-doctoral departments in
predominantly undergraduate institutions.
Charles Beam and Shannon Martinez reecievd $145,000 from teh NSF-RUI program.
The focus of their work is the preparation of benzopyranones, benzothiopyranones, benzoquinolines and
benzacridines, compounds with potential for intramolecular proton transfer in the electronic excited
state. Many of the proposed target molecules have potential as radiation scintillators, luminescent solar
concentrators and laser dyes. The students working on the project will have the experience of conducting
organic synthesis and carrying out steady-state and time-resolved spectroscopic studies on many of the
compounds prepared. With this Research in Undergraduate Institutions (RUI) award, the Synthetic
Organic Program is supporting the research of Drs. Charles F. Beam and Shannon S. Martinez of the
Department of Chemistry at the College of Charleston. Work will focus on the preparation and
photophysical study of heterocyclic compounds with the goal of understanding intramolecular proton
transfer in the electronic excited state. The research will serve to enhance the education of a number of
undergraduate participants
Kristin Krantzman is supported by a $121,500 RUI grant from the Theoretical and Computational Chemistry
Program to perform molecular dynamics simulations of the high-energy bombardment of organic targets
on Cu(001) microcrystallites with polyatomic projectiles. She will examine the emission yield of
molecules and molecular fragments, and estimate the surface damage. She will also study the energy
deposition into the solid and the distribution of energy density in the solid support. The objective of the
research is to shed additional light on the mechanism of Secondary Ion Mass Spectroscopy (SIMS) and
Fast Atom Bombardment Mass Spectroscopy (FABMS). A good portion of the work will be performed
in collaboration with Barbara Garrison at Penn State University. SIMS and FABMS are analytical mass
spectroscopic sampling techniques that are used in such diverse research applications as imaging human
blood cells, detecting pesticide residues on leaves and soil, and analyzing the composition of Martian
meteorites and the processing of semiconductor devices. Through the use of molecular dynamics
simulations, Krantzman will elucidate the fundamental processes that occur at the molecular level in
these sampling techniques.
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